bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI)) | 88548-75-8

• 英文名称: bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))
• CAS: 88548-75-8
• 化学式: 2C₂₄H₂₀P*Cl₂FeS₄W
• 分子量: 1117.66
• InChiKey: HTUVXVIECAMJAA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI)) 、 iron(II) chloride 以 乙腈 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  Coucouvanis; Simhon; Stremple, Inorganic Chemistry, 1984, vol. 23, # 6, p. 741 - 749

  摘要：

  DOI：
• 作为产物：
  描述：

  tetraphenylphosphonium tetrathiotungstate 、 以 乙腈 为溶剂， 以95%的产率得到bis(tetraphenylphosphonium) bis(μ-thio)(dichloroferrate(II)dithiotungstate(VI))
  参考文献：
  名称：

  Coucouvanis; Simhon; Stremple, Inorganic Chemistry, 1984, vol. 23, # 6, p. 741 - 749

  摘要：

  DOI：

文献信息

• Synthesis and characterization of the bimetallic series
  作者：Eddy Dumas、Jérôme Marrot、Josseline Jullien、Francis Sécheresse

  DOI：10.1016/j.ica.2004.07.017

  日期：2005.1

  A series of thioheterobimetallic anions have been synthesized: [S2WS2Fe(NCS)X](2-) (X = Cl- (1); X = NCS- (2); X = N-3(-) (3)). The molecular dianions were isolated by substitution in [S2WS2FeCl2](2-) of the labile terminal chloro ligands by NCS- and/or N-3(-). Anions (1) and (3) are the first iron tris-heteroleptic complexes of the well-known [S2WS2FeX2](2-) (M = Mo, W) family. The structures of the three molecular anions, isolated as tetraphenylphosphonium salts, are reported, as well as characterization by IR, electronic and electrospray mass spectroscopies. (C) 2004 Elsevier B.V. All rights reserved.
• Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten). First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site
  作者：D. Coucouvanis、N. C. Baenziger、E. D. Simhon、P. Stremple、D. Swenson、A. Simopoulos、A. Kostikas、V. Petrouleas、V. Papaefthymiou

  DOI：10.1021/ja00525a050

  日期：1980.2