| 55620-69-4

• CAS: 55620-69-4；32408-83-6
• 化学式: F₆Ti*H₁₂NiO₆
• 分子量: 328.652
• InChiKey: NPDFFDLDCYZOAT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  镍,[碳酸(2-)-κO]- 、 hexafluorotitanic acid 在 水 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Cheung, Hsueh Mei; Lichti, R. L., Journal of Physics C: Solid State Physics

  摘要：

  DOI：

文献信息

• Crystal growth in aqueous hydrofluoric acid and (HF)x · pyridine solutions: syntheses and crystal structures of [Ni(H2O)6]2+[MF6]2− (M = Ti, Zr, Hf) and Ni3(py)12F6 · 7H2O
  作者：Paramasivan Halasyamani、Michael J. Willis、Charlotte L. Stern、Kenneth R. Poeppelmeier

  DOI：10.1016/0020-1693(95)04650-x

  日期：1995.12

  The syntheses and structures of [Ni(H2O)(6)](2+)[MF(6)](2-)(M = Ti, Zr, Hf) and Ni-3(py)(12)F-6 . 7H(2)O are reported. The former three compounds are isostructural, crystallizing in the trigonal space group (No. 148) with Z = 3. The lattice parameters are a = 9.489(4), c = 9.764(7) Angstrom, with V = 761(1) Angstrom(3) for Ti;a = 9.727(2), c = 10.051 (3) Angstrom, With V = 823.6(6) Angstrom(3) for Zr; and a = 9.724(3), c = 10.028(4) Angstrom, with V = 821.2(8) Angstrom(3) for Hf. The structures consist of discrete [Ni(H2O)(6)](2+) and [MF(6)](2-) octahedra joined by O-H ... F hydrogen bonds. Large single crystals were grown in an aqueous hydrofluoric acid solution. Ni-3(PY)(12)F-6 . 7H(2)O crystallizes in the monoclinic space group I2/a (No. 15) with Z = 4. The lattice parameters are a = 16.117(4), b = 8.529(3), c = 46.220(7) Angstrom, beta = 92.46(2)degrees, and V = 6348(5) Angstrom(3). The structure consists of discrete Ni(py)(4)F-2 octahedra linked through H-O-H ... F and H-O-H ... O hydrogen bonding interactions. Single crystals were grown from a (HF)(x) . pyridine/pyridine/water solution.