[Pd(η3-CH(C6H5)CHCH(OSi(CH3)3))(P(C6H5)3)2]SO3CF3 | 474662-62-9

• 英文名称: [Pd(η3-CH(C6H5)CHCH(OSi(CH3)3))(P(C6H5)3)2]SO3CF3
• CAS: 474662-62-9
• 化学式: CF₃O₃S*C₄₈H₄₇OP₂PdSi
• 分子量: 985.424
• InChiKey: CXKNJUMZQAPBJP-TXIOGCIWSA-M

反应信息

• 作为产物：
  描述：

  Pd(η2-CH(C6H5)CHCO)(P(C6H5)3)2 、 三氟甲磺酸三甲基硅酯 以 氘代苯 为溶剂， 以99%的产率得到[Pd(η3-CH(C6H5)CHCH(OSi(CH3)3))(P(C6H5)3)2]SO3CF3
  参考文献：
  名称：

  Palladium/Me₃SiOTf-Catalyzed Bis-silylation of α,β-Unsaturated Carbonyl Compounds without Involving Oxidative Addition of Disilane

  摘要：

  In the presence of a catalytic amount of Me(3)SiOTf and palladium(0), the addition of disilane to alpha,beta-unsaturated carbonyl compounds proceeds under very mild conditions via eta(3)-siloxyallylpalladium generated by the reaction of enone, enal, or aromatic aldehyde with palladium and Me(3)SiOTf.

  DOI：

  10.1021/ja0272944