| 200950-98-7

• CAS: 200950-98-7；772336-04-6
• 化学式: C₃₄H₃₂Mn₂N₄O₆
• 分子量: 702.527
• InChiKey: DTTNHVBYFILRLG-MFMGSHIISA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  potassium permanganate 、 N,N’-双亚水杨-1,2-丙二胺 以 乙腈 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Preparation and characterization of different two types of di-μ-oxo dimanganese(IV) complexes with tetradentate Schiff bases

  摘要：

  Novel di-mu-oxo dimanganese(IV) complexes with a series of tetradentate Schiff base ligands have been prepared and characterized by spectroscopy, magnetic susceptibility, electrochemical measurements and X-ray crystallography. The di-mu-oxo dimanganese(IV) complexes, [Mn-IV(mu-salophen)(mu-O)], 1 (salophen H-2 = N,N'-disalicylidene-1,2-diaminobenzene), [Mn(mu-salen)(mu-O)](2), 2 (salenH(2) = N,N'-disalicylidene-1,2-diaminoethane), [Mn(salen)(mu-O)](2), 3, [Mn(salipn)(mu-O)](2), 4 (salipnH(2) = N,N'-disalicylidene-1,2-diaminopropane) and [Mn(salbn)(mu-O)](2), 5 (salbnH(2) = N,N'-disalicylidene-1,4-diaminobutane), have been found to be obtained by the reaction of the tetradentate Schiff base ligands and potassium permanganate (KMnO4) in MeCN with stirring at room temperature. X-ray analysis revealed that these complexes are classified by two different types of di-mu-oxo manganese(IV) complexes in the coordination features of the ligands: one of them (1 and 2) has a structure in which salophen or salen ligands are coordinated to two manganese ions as a bridging bidentate ligand, whereas the other (3, 4 and 5) has a structure in which salen, salipn or salbn ligands are coordinated to each manganese ion as a tetradentate ligand. These types were characterized from their IR spectra around 650 cm(-1), UV-vis spectra and electrochemical properties. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00247-7