(R)-[TpRe(CO)(MeIm)(η(2)-C10H9C(CH3)2COOCH3)] | 431041-17-7

• 英文名称: (R)-[TpRe(CO)(MeIm)(η(2)-C10H9C(CH3)2COOCH3)]
• 英文别名: (R)-[(hydrotris(pyrasolyl)borate)Re(CO)(1-methylimidazole)(η(2)-C10H9C(CH3)2COOCH3)]
• CAS: 431041-17-7
• 化学式: C₂₉H₃₄BN₈O₃Re
• 分子量: 739.659
• InChiKey: RFOMVMYXUUWREO-AHJYMZSGSA-N

反应信息

• 作为产物：
  描述：

  1-甲氧基-1-(三甲基甲硅氧基)-2-甲基-1-丙烯 、 [(hydridotris(pyrazolyl)borate)Re(CO)(N-imethylimidazole)pyridine)(1,2-η(2)-naphthalene)] 在 lutidine 作用下， 以 not given 为溶剂， 生成 (R)-[TpRe(CO)(MeIm)(η(2)-C10H9C(CH3)2COOCH3)]
  参考文献：
  名称：

  Strategy for the Resolution of a Chiral Dearomatization Agent:{TpRe(CO)(1-methylimidazole)} Coordination of α-Pinene (Tp = Hydridotris(pyrazolyl)borate)

  摘要：

  A methodology for resolving TpRe(CO)(1-methylimidazole)(eta(2)-benzene) has been developed utilizing (R)-alpha-pinene. Each enantiomer of the {TpRe(CO)(Melm)} system can be obtained with the enantiomer ratio (er) = 97:3 by taking advantage of differing rates of pinene substitution for the two diastereomers of TpRe(CO)(Melm)(eta(2)-(R)-alpha-pinene).

  DOI：

  10.1021/ja0118845