[3]-ferrocenophane-2-phenylimine | 262300-29-8

• 英文名称: [3]-ferrocenophane-2-phenylimine
• CAS: 262300-29-8
• 化学式: C₁₉H₁₇FeN
• 分子量: 315.198
• InChiKey: URIBWLLEGJBOOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [3]-ferrocenophane-2-phenylimine 、 lithium aluminium tetrahydride 以 乙醚 为溶剂， 以95%的产率得到2-(n-phenyl)amino-[3]-ferrocenophane
  参考文献：
  名称：

  Dissociative Intramolecular Charge Transfer after Local Two-Photon Ionization of Ferrocene Derivatives with Aromatic Chromophores

  摘要：

  Experimental evidence for dissociative intramolecular charge transfer processes is found for gas-phase ferrocene-aniline derivatives after local ionization at the aniline chromophore site via intermediate states with predominant aniline character. The direct ionization at the ferrocene site can be excluded since there is a rapid dissociation of ferrocene in the intermediate state prior to ionization so that no ferrocene ions would be produced in this case. Because of the higher local ionization energy of the chromophore, charge transfer takes place after local ionization. The released energy and additional photon absorption leads to breaking of bonds and results in a dissociation into intact ferrocene or ferrocene-containing cations and neutral fragments.

  DOI：

  10.1021/jp992963u
• 作为产物：
  描述：

  [3]-ferrocenophan-6-one 、 苯胺 在 zinc(II) chloride 作用下， 以 甲苯 为溶剂， 以78%的产率得到[3]-ferrocenophane-2-phenylimine
  参考文献：
  名称：

  Dissociative Intramolecular Charge Transfer after Local Two-Photon Ionization of Ferrocene Derivatives with Aromatic Chromophores

  摘要：

  Experimental evidence for dissociative intramolecular charge transfer processes is found for gas-phase ferrocene-aniline derivatives after local ionization at the aniline chromophore site via intermediate states with predominant aniline character. The direct ionization at the ferrocene site can be excluded since there is a rapid dissociation of ferrocene in the intermediate state prior to ionization so that no ferrocene ions would be produced in this case. Because of the higher local ionization energy of the chromophore, charge transfer takes place after local ionization. The released energy and additional photon absorption leads to breaking of bonds and results in a dissociation into intact ferrocene or ferrocene-containing cations and neutral fragments.

  DOI：

  10.1021/jp992963u