eq-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)] | 866367-60-4

• 英文名称: eq-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]
• 英文别名: eq-[Re2(CO)9(η1-PPh2(CH2)3P(o-anisyl)2)]；ax-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]；ax-[Re2(CO)9(η1-(P(o-anisyl)2(CH2)3PPh2)]
• CAS: 866367-60-4；866367-61-5；866915-74-4
• 化学式: C₃₈H₃₀O₁₁P₂Re₂
• 分子量: 1097.01
• InChiKey: WELRMWFWRWEUAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  eq-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)] 以 二氯甲烷 为溶剂， 生成 ax-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]
  参考文献：
  名称：

  Rhenium carbonyl complexes with monodentate-coordinated diphosphines: activation of terminal phosphino groups towards amine-oxide oxidation

  摘要：

  Terminal phosphino groups of [Re-2(CO)(9)(eta(1)-P-P)] (P-P = diphosphines) are activated towards oxidation by Me3NO. The respective reactions of MC3NO with [Re-2(CO)(9){eta(1)-P(o-anisyl)(2)(CH2)PPh2}], [Re-2(CO)(9){eta(1)-PPh2(CH2)(3)P(o-anisyl)(2)}] and [Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] were studied to investigate the mechanism of this oxidation. The results are consistent with an intramolecular pathway involving a cyclic intermediate, without exchange of the coordinated and terminal phosphino groups. A mechanism which involves an interaction of the terminal phosphino group with a carbonyl ligand is proposed. In sharp contrast to eq-[Re-2(CO)(9)(eta(1)-P-P)] (P-P = Ph2P(CH2)(n)PPh2, n = 1-6), eq-[Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] appears to be indefinitely stable towards equatorial -> axial isomerization at room temperature, thus, allowing its crystal structure to be determined. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.010
• 作为产物：
  描述：

  ax-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)] 、 氧气 以 二氯甲烷 为溶剂， 生成 eq-[Re2(CO)9(η1-(1-(di-o-anisylphosphino)-3-(diphenylphosphino)propane)]
  参考文献：
  名称：

  Rhenium carbonyl complexes with monodentate-coordinated diphosphines: activation of terminal phosphino groups towards amine-oxide oxidation

  摘要：

  Terminal phosphino groups of [Re-2(CO)(9)(eta(1)-P-P)] (P-P = diphosphines) are activated towards oxidation by Me3NO. The respective reactions of MC3NO with [Re-2(CO)(9){eta(1)-P(o-anisyl)(2)(CH2)PPh2}], [Re-2(CO)(9){eta(1)-PPh2(CH2)(3)P(o-anisyl)(2)}] and [Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] were studied to investigate the mechanism of this oxidation. The results are consistent with an intramolecular pathway involving a cyclic intermediate, without exchange of the coordinated and terminal phosphino groups. A mechanism which involves an interaction of the terminal phosphino group with a carbonyl ligand is proposed. In sharp contrast to eq-[Re-2(CO)(9)(eta(1)-P-P)] (P-P = Ph2P(CH2)(n)PPh2, n = 1-6), eq-[Re-2(CO)(9)(eta(1)-trans-PPh2CH=CHPPh2)] appears to be indefinitely stable towards equatorial -> axial isomerization at room temperature, thus, allowing its crystal structure to be determined. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.010