[Ru(CO)(tert-butylisonitrile)(B(methimazolyl)3)] | 1009306-00-6

• 英文名称: [Ru(CO)(tert-butylisonitrile)(B(methimazolyl)3)]
• CAS: 1009306-00-6
• 化学式: C₁₈H₂₄BN₇ORuS₃
• 分子量: 562.514
• InChiKey: GNJSWYXVOMIOCM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  [Ru(CO)(PPh₃){B(N-methyl-2-mercaptoimidazolyl)₃}] 、 异氰酸叔丁酯 以 二氯甲烷 为溶剂， 以32%的产率得到[Ru(CO)(tert-butylisonitrile)(B(methimazolyl)3)]
  参考文献：
  名称：

  Synthesis of the Ruthenaboratranes [Ru(CS)(PPh₃){B(mt)₃}](Ru→B)⁸ and [Ru(CO)(CNR){B(mt)₃}](Ru→B)⁸ (mt = methimazolyl, R = ^tBu, C₆H₃Me₂-2,6, C₆H₂Me₃-2,4,6)

  摘要：

  The reaction of [Ru(CH=CH2)Cl(CS)(PPh3)(2)] with Na[HB(mt)(3)] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)(3)}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)(2){B(mt)(3)}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt(3))}] (R = Bu-t, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)(3)}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)(3)}], [Ru(CO)((CNBu)-Bu-t)({B(mt)(3)}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)(3)}] are reported.

  DOI：

  10.1021/om7008777