N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide | 867277-65-4

• 英文名称: N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide
• CAS: 867277-65-4
• 化学式: C₃₀H₃₈Fe₂N₄O₂
• 分子量: 598.351
• InChiKey: WFWLJSGYWQQQGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  zinc(II) perchlorate 、 N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide 在 sodium hydroxide 作用下， 以 1,4-二氧六环 为溶剂， 生成 [Zn(II)(N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide(2-))]
  参考文献：
  名称：

  Ferrocene substituted N,N′-bis(3-aminopropyl)oxamide: A new electrochemical sensor for copper(II) and fluoride ions in the biological pH range

  摘要：

  A new pH responsive ferrocene functionalized receptor N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide (R) was synthesized and characterized. The electrochemical responses of the receptor R as a function of pH have been determined using cyclic voltammetric technique. Increase in H+ ion concentration in the medium increases the redox potential of the Fc/Fc(+) redox couple of the receptor. Addition of metal ions like Mn(II), Ni(II) and Zn(II) show anodic shift of the Fc/Fc(+) redox couple. The presence of Cu(II) ion shows cathodic shift of the Fc/Fc(+) redox couple at acidic pH values. The potential shifts between the free receptor and the receptor with anions (F-, Cl- and Br-) at different pH were determined. Among the halide anions, fluoride ion shows appreciable amount of cathodic potential shift. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.01.027
• 作为产物：
  描述：

  二茂铁甲醛 、 N¹,N²-bis(3-aminopropyl)oxalamide 、 sodium tetrahydroborate 以 乙醇 为溶剂， 以65%的产率得到N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide
  参考文献：
  名称：

  Ferrocene substituted N,N′-bis(3-aminopropyl)oxamide: A new electrochemical sensor for copper(II) and fluoride ions in the biological pH range

  摘要：

  A new pH responsive ferrocene functionalized receptor N,N'-bis(3-ferrocenylmethyl aminopropyl)oxamide (R) was synthesized and characterized. The electrochemical responses of the receptor R as a function of pH have been determined using cyclic voltammetric technique. Increase in H+ ion concentration in the medium increases the redox potential of the Fc/Fc(+) redox couple of the receptor. Addition of metal ions like Mn(II), Ni(II) and Zn(II) show anodic shift of the Fc/Fc(+) redox couple. The presence of Cu(II) ion shows cathodic shift of the Fc/Fc(+) redox couple at acidic pH values. The potential shifts between the free receptor and the receptor with anions (F-, Cl- and Br-) at different pH were determined. Among the halide anions, fluoride ion shows appreciable amount of cathodic potential shift. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.01.027