[NiCl2(dibenzo[g,p]dinaphtho[1,8-bc:1,8-kl][1,5,10,14]tetraazacyclooctadecine)] | 1043461-06-8

• 英文名称: [NiCl2(dibenzo[g,p]dinaphtho[1,8-bc:1,8-kl][1,5,10,14]tetraazacyclooctadecine)]
• CAS: 1043461-06-8
• 化学式: C₃₆H₂₄Cl₂N₄Ni
• 分子量: 642.209
• InChiKey: YOWSSTZOCIXHRD-CTSGTPBFSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) chloride hexahydrate 、 dibenzo[g,p]dinaphtho-[1,8-bc:1,8-kl][1,5,10,14]-tetraazacyclooctadecine 以 甲醇 为溶剂， 以75%的产率得到[NiCl2(dibenzo[g,p]dinaphtho[1,8-bc:1,8-kl][1,5,10,14]tetraazacyclooctadecine)]
  参考文献：
  名称：

  Catalytic reduction of pralidoxime in pharmaceuticals by macrocyclic Ni(II) compounds derived from orthophthalaldehyde

  摘要：

  Efficient catalytic method for the reduction of pralidoxime to its amine derivative by macrocyclic Ni(II) compounds has been developed. Ten macrocyclic Schiff base Ni(II) compounds were synthesized via non-template synthesis by treating the corresponding macrocycles with nickel chloride in 1:1 ratio. The resulting compounds were characterized by elemental, IR, H-1 NMR, C-13 NMR, mass, electronic spectra, conductance, magnetic, thermal studies and their structures have been proposed. These compounds were used as catalysts for the reduction of pralidoxime to its amino derivative. The reduced pralidoxime was also characterized by spectral analysis and catalytic cycle has been established. The reduced product was determined spectrophotometrically by treating with ninhydrin reagent and the percent yields were found to be in the range of 75.12-82.36%. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.10.014