([η-C5H4CHN(C6F5)]Fe[η5-C5H4PPh2])2Ni2Cl | 942597-20-8

• 英文名称: ([η-C5H4CHN(C6F5)]Fe[η5-C5H4PPh2])2Ni2Cl
• CAS: 942597-20-8
• 化学式: C₅₈H₃₈ClF₁₀Fe₂N₂Ni₂P₂
• 分子量: 1279.41
• InChiKey: WWRFMNMVEMWTLW-AZNOENIWSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 [[η-C5H4CH=N(C6F5)]Fe[η-C5H4PPh2]] 在 AlCl₃ 作用下， 以 甲苯 为溶剂， 以57%的产率得到([η-C5H4CHN(C6F5)]Fe[η5-C5H4PPh2])2Ni2Cl
  参考文献：
  名称：

  A Strange Nickel(I)−Nickel(0) Binuclear Complex and Its Unexpected Ethylene Oligomerization

  摘要：

  The unusual heterovalent bimetallic Ni-I-Ni-0 complex {[eta-C5H4CHN(C6F5)]Fe[eta-C5H4PPh2]}(2)Ni-2(Cl) (2) was isolated from the reaction between [eta-C5H4CHN(C6F5)]Fe[eta-C5H4PPh2] (1) and Ni(COD)(2) in the presence of AlEtCl2 or AlCl3. Complex 2 has been crystallographically characterized and theoretically analyzed; it is catalytically active (TOF 90 500) and selective (91%) toward the formation of C-4 oligomers from ethylene (300 psi) at 30 degrees C, the only other significant isomer formed being C-6.

  DOI：

  10.1021/om0701322