| 1007391-47-0

• CAS: 1007391-47-0
• 化学式: C₂₂H₂₀FeN₂O₂S
• 分子量: 432.326
• InChiKey: BLSKLVYMRGWUIZ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  在 sodium ethoxide 、 HCl 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  “Push–pull” 2-ferrocenyl-4-hydroxythiazoles: A novel method of the construction of the thiazole ring

  摘要：

  The title compounds were obtained by cyclization of ferrocenyl thioimidates in the presence of sodium ethoxide. They were transformed into the corresponding 4-acetoxy-derivatives in reaction with acetic anhydride/pyridine. The structure of 4-acetoxy-5-(ethoxycarbonyl)-2-ferrocenylthiazole was determined by X-ray diffraction. The EFISH measurements revealed significant second-order nonlinear properties of 4-acetoxy-2-ferrocenyl-5-(4-nitrophenyl)ferrocenylthiazole (mu beta = 250 x 10(48) esu at 1907 nm). (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.04.043