CdCl2(N-(5,6-dihydro-4H-1,3-thiazin-2-yl)-2-aminobenzimidazole)2 | 866926-13-8

• 英文名称: CdCl2(N-(5,6-dihydro-4H-1,3-thiazin-2-yl)-2-aminobenzimidazole)2
• 英文别名: CdCl2(BzTz)2
• CAS: 866926-13-8
• 化学式: C₂₂H₂₄CdCl₂N₈S₂
• 分子量: 647.934
• InChiKey: CEIZCWHFCAUKPY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  aqueous cadmium chloride 、 N-(5,6-dihydro-4H-1,3-thiazin-2-yl)-2-aminobenzimidazole 以 甲醇 为溶剂， 以44.9%的产率得到CdCl2(N-(5,6-dihydro-4H-1,3-thiazin-2-yl)-2-aminobenzimidazole)2
  参考文献：
  名称：

  Cobalt(II) and cadmium(II) metal complexes of a 2-aminobenzimidazole-thiazine derivative ligand. Synthesis, characterization and X-ray structure determinations

  摘要：

  The characterization of N-(5,6-dihydro-4H-1,3-thiazin-2-yl)-2-aminobenzimidazole (BzTz) has been carried out by means of physical measurements and single X-ray diffraction. This ligand possesses three potential donor nitrogen atoms in its structure. Contrary to what was expected, BzTz acts as a monodentate ligand through nitrogen atom of benzimidazole ring. Moreover, the metal complexes [COCl2(BzTz)(2)] and [CdCl2(BzTz)(2)] have been prepared and characterized by a variety of physico-chemical techniques. Likewise, the structures have been determined by X-ray diffraction. The environment around the cobalt(II) and cadmium(II) atoms may be described as a distorted tetrahedral geometry with the metallic atom coordinated to two chlorine atoms, and two benzimidazole nitrogen atoms. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.05.011