[(η(6)-phenyltrimethylsilane)Mn(CO)3]BF4 | 167284-79-9

• 英文名称: [(η(6)-phenyltrimethylsilane)Mn(CO)3]BF4
• CAS: 167284-79-9
• 化学式: BF₄*C₁₂H₁₄MnO₃Si
• 分子量: 376.069
• InChiKey: WAZGCZGHBGOFDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基溴化锰(I) 、 三甲基苯基硅烷 、 silver tetrafluoroborate 以 二氯甲烷 为溶剂， 以56%的产率得到[(η(6)-phenyltrimethylsilane)Mn(CO)3]BF4
  参考文献：
  名称：

  Synthesis of manganese and ruthenium complexes of phenyltrimethylsilane, diphenyltetramethyldisilane and poly(methylphenylsilane)

  摘要：

  The reaction of [Mn(CO)(5)](+) with phenyltrimethylsilane (L-1) or diphenyltetramethyldisilane (L-2) affords [Mn(CO)(3)L-1][BF4] and [Mn(CO)(3)L-2][BF4] in which the silane ligand is eta(6)-coordinated via an aromatic ring. A similar procedure using poly(methylphenylsilane) (PMPS) as the ligand resulted in very low incorporation of Mn(CO)(3)(+) fragments into the polymer. A loading of 10% was achieved, however, by using [(naphthalene)Mn(CO)(3)][BF4] as a Mn(CO)(3)(+) transfer reagent to form the copolymer poly(methylphenylsilane-stat-methyl(eta(6)-phenyltricarbonylmanganesetetrafluoroborate)silane). Reaction of [(p-cymene)Ru(O3SCF3)(2)](x) (p-cymene = 4-isopropyltoluene) with L-1 affords air sensitive [Ru(p-cymene)L-1][O3SCF3](2). Higher yields of the related complex [Ru(p-cymene)L-1][BF4](2) were obtained by addition of L-1 to a mixture of [(p-cymene)RuCl2](2) and AgBF4. Only poorly characterised copolymers containing ruthenium were obtained by analogous reactions with PMPS. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00347-1