| 156919-64-1

• CAS: 156919-64-1
• 化学式: C₃₂H₃₈Cl₂N₁₁NiP₃
• 分子量: 799.245
• InChiKey: ZJZVZICOGUFYJN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2,4,4-Tetrakis(3,5-dimethylpyrazolyl)-6,6-diphenyl-2λ⁵,4λ⁵,6λ⁵-cyclotriphosphaza-1,3,5-triene 、 nickel dichloride 以 二氯甲烷 为溶剂， 以69%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of mononuclear nickel(II) and cobalt(II) complexes of 2,2,4,4-tetrakis(3,5-dimethylpyrazolyl)-6,6-diphenyl-2λ⁵,4λ⁵,6λ⁵-cyclotriphosphaza-1,3,5-triene L: crystal structure of [NiLCl₂]

  摘要：

  Three complexes [NiLCl2] 2a, [NiLBr2] 2b and [CoLCl2] 2c, where L is the potentially multidentate ligand 2,2,4,4-tetrakis(3,5-dimethylpyrazolyl)-6,6-diphenyl-2lambda5,4lambda5,6lambda5-cyclotriphosphaza-1,3,5-triene, have been prepared and characterized spectroscopically (IR, H-1 and P-31 NMR) and in the case of 2a, crystallographically. The Ni(II) atom in 2a has been shown to exist in a distorted trigonal-bipyramidal geometry in which the halide atoms and a ring nitrogen atom define the equatorial plane; the axial positions are occupied by two nitrogen atoms derived from two pyrazolyl rings. Crystals of 2a are monoclinic with space group C2/c and unit cell dimensions: a = 38.190(8), b = 9.225(3), c = 21.830(4) angstrom, beta = 108.29(2)-degrees and Z = 8. The structure was refined to final R = 0.045 for 4414 observed data.

  DOI：

  10.1039/dt9940001301