[bis(N,N-bis(2-pyridylmethyl)-N'-salicylidenate-ethane-1,2-diamine)chloromanganese(III)] | 881736-73-8

• 英文名称: [bis(N,N-bis(2-pyridylmethyl)-N'-salicylidenate-ethane-1,2-diamine)chloromanganese(III)]
• 英文别名: [(N,N-bis(2-pyridylmethyl)-N'-salicylideneethane-1,2-diamine(-1H))Mn(III)Cl](1+)
• CAS: 881736-73-8
• 化学式: C₂₁H₂₁ClMnN₄O
• 分子量: 435.815
• InChiKey: UUKTYLQYFFHIFK-IFGMWRHRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 [bis(N,N-bis(2-pyridylmethyl)-N'-salicylidenate-ethane-1,2-diamine)chloromanganese(III)] 以 乙腈 为溶剂， 生成 [(N,N-bis(2-pyridylmethyl)-N'-salicylideneethane-1,2-diamine)Mn(II)Cl2]
  参考文献：
  名称：

  Influence of the Electrochemical Conversion of [(LH)Mn^IICl₂] into [(L)Mn^IIICl]⁺ on the Protonic State of a Phenol-Containing Ligand

  摘要：

  A bischloromanganese(II) complex [(LH)MnCl2] (1), where LH is the pentadentate ligand N,N-bis(2-pyridyimethyl)-N'-salicylidene-ethane- 1,2-diamine, has been synthesized. Elemental analysis, UV-visible, and cyclic voltammetry experiments showed that the phenol function of the ligand LH remains protonated. Exhaustive electrolysis at 1.0 V vs SCE led to the formation of the Mn-III derivative [(L)MnCl](+) (3) with the concomitant expulsion of H+ and Cl-. The formation of the Mn-III species was confirmed by UV-visible spectroscopy and X-ray crystallography. Complex 1 could be regenerated by the reduction of complex 3 in the presence of H+ and Cl-.

  DOI：

  10.1021/ic051882b
• 作为产物：
  描述：

  [(N,N-bis(2-pyridylmethyl)-N'-salicylideneethane-1,2-diamine)Mn(II)Cl2] 以 乙腈 为溶剂， 以85%的产率得到[bis(N,N-bis(2-pyridylmethyl)-N'-salicylidenate-ethane-1,2-diamine)chloromanganese(III)]
  参考文献：
  名称：

  Influence of the Electrochemical Conversion of [(LH)Mn^IICl₂] into [(L)Mn^IIICl]⁺ on the Protonic State of a Phenol-Containing Ligand

  摘要：

  A bischloromanganese(II) complex [(LH)MnCl2] (1), where LH is the pentadentate ligand N,N-bis(2-pyridyimethyl)-N'-salicylidene-ethane- 1,2-diamine, has been synthesized. Elemental analysis, UV-visible, and cyclic voltammetry experiments showed that the phenol function of the ligand LH remains protonated. Exhaustive electrolysis at 1.0 V vs SCE led to the formation of the Mn-III derivative [(L)MnCl](+) (3) with the concomitant expulsion of H+ and Cl-. The formation of the Mn-III species was confirmed by UV-visible spectroscopy and X-ray crystallography. Complex 1 could be regenerated by the reduction of complex 3 in the presence of H+ and Cl-.

  DOI：

  10.1021/ic051882b