[Pd2(μ-SeMes)2(η3-metallyl)2] | 1036999-81-1

• 英文名称: [Pd2(μ-SeMes)2(η3-metallyl)2]
• CAS: 1036999-81-1
• 化学式: C₂₆H₃₆Pd₂Se₂
• 分子量: 719.332
• InChiKey: CJHKRSWJOHGTHD-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Pd2(μ-SeMes)2(η3-metallyl)2] 以 neat (no solvent, solid phase) 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and Characterization of Chalcogenolato-Bridged Allyl Palladium Complexes: Versatile Precursors for Palladium Chalcogenides

  摘要：

  The complexes [Pd(mu-ER)(eta(3)-allyl)](2) (ER = EMes; E = S, Se, allyl = C3H5, C4H7) have been isolated by the reaction of [Pb(ER)(2)](n) with [Pd-2(mu-Cl)(2)(eta(3)-allyl)(2)]. Similar reactions with [Pb(SeCH2CH2NMe2)(2)](n) resulted in the formation of a trinuclear complex [Pd3Cl2(kappa(2) -Se,N-SeCH2CH2NMe2)(eta(3)-allyl)(3)]. Treatment of [Pd(mu-SR)(eta(3)-C4H7)](2) with [Pd(SMes)(2)](n) in 1:1 ratio yielded [Pd-3(mu-SMes)(4)(eta(3)-C4H7)(2)]. These complexes were characterized by elemental analyses and mass, UV-vis, and NMR spectroscopy. The structures of [Pd-2(mu-EMes)(2)(eta(3)-C4H7)(2)] (E = S, Se) were established by single-crystal X-ray diffraction analysis, which revealed a syn configuration. Two new structural motifs for [Pd3Cl2(kappa(2)-Se,N-SeCH2CH2NMe2)(eta(3)-C3H5)(3)] and [Pd-3(mu-SMes)(4)(eta(3)-C4H7)(2)] have also been identified. Pyrolysis of [Pd(mu-ER)(eta(3)-C4H7)](2) yielded palladium chalcogenides, which were characterized by powder XRD and EDAX.

  DOI：

  10.1021/om8000795
• 作为产物：
  描述：

  (2-methylallyl)palladium-chloride dimer 、 以 苯 为溶剂， 生成 [Pd2(μ-SeMes)2(η3-metallyl)2]
  参考文献：
  名称：

  Synthesis and Characterization of Chalcogenolato-Bridged Allyl Palladium Complexes: Versatile Precursors for Palladium Chalcogenides

  摘要：

  The complexes [Pd(mu-ER)(eta(3)-allyl)](2) (ER = EMes; E = S, Se, allyl = C3H5, C4H7) have been isolated by the reaction of [Pb(ER)(2)](n) with [Pd-2(mu-Cl)(2)(eta(3)-allyl)(2)]. Similar reactions with [Pb(SeCH2CH2NMe2)(2)](n) resulted in the formation of a trinuclear complex [Pd3Cl2(kappa(2) -Se,N-SeCH2CH2NMe2)(eta(3)-allyl)(3)]. Treatment of [Pd(mu-SR)(eta(3)-C4H7)](2) with [Pd(SMes)(2)](n) in 1:1 ratio yielded [Pd-3(mu-SMes)(4)(eta(3)-C4H7)(2)]. These complexes were characterized by elemental analyses and mass, UV-vis, and NMR spectroscopy. The structures of [Pd-2(mu-EMes)(2)(eta(3)-C4H7)(2)] (E = S, Se) were established by single-crystal X-ray diffraction analysis, which revealed a syn configuration. Two new structural motifs for [Pd3Cl2(kappa(2)-Se,N-SeCH2CH2NMe2)(eta(3)-C3H5)(3)] and [Pd-3(mu-SMes)(4)(eta(3)-C4H7)(2)] have also been identified. Pyrolysis of [Pd(mu-ER)(eta(3)-C4H7)](2) yielded palladium chalcogenides, which were characterized by powder XRD and EDAX.

  DOI：

  10.1021/om8000795