[Cu(5-phenyl-6-phenyethynyl-2,2'-bipyridine)Cl2] | 878498-04-5

• 英文名称: [Cu(5-phenyl-6-phenyethynyl-2,2'-bipyridine)Cl2]
• CAS: 878498-04-5
• 化学式: C₂₄H₁₆Cl₂CuN₂
• 分子量: 466.856
• InChiKey: GZXHZTXGTPEWPS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-phenyl-6-phenylethynyl-2,2'-bipyridine 、 copper(II) choride dihydrate 以 乙腈 为溶剂， 以88%的产率得到[Cu(5-phenyl-6-phenyethynyl-2,2'-bipyridine)Cl2]
  参考文献：
  名称：

  CuCl2 induced reactions of 6-ethynyl- and 6-cyano-5-aryl-2,2′-bipyridines with various N- and O-nucleophiles in comparison with the reactions of relative 1,2,4-triazines

  摘要：

  Meanwhile 5-aryl-6-cyano-2,2'-bipyridines are very stable towards various nucleophiles, addition copper(II) chloride to the reactional mixture facilitates nucleophilic addition to the cyano group dramatically. The cyanobipyridines react easily with water, methanol, ethanolamine in the presence of CuCl2 yielding well-crystallized complexes containing carboxylates, carboximidates or carboxamidines as ligands. 5-Cyano-1,2,4-triazines are more active in the reactions due to higher electron-withdrawing properties of this heterocycle. Due to the same reason acetylene moiety of 5-ethynyl-3-pyridyl-1,2,4-triazine adds water quite easily but in the presence of copper chloride as well. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.02.016