[Rh((S,S)-DIPAMP)((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF4 | 863615-57-0

• 英文名称: [Rh((S,S)-DIPAMP)((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF4
• CAS: 863615-57-0
• 化学式: BF₄*C₄₇H₄₇NO₇P₂Rh
• 分子量: 989.55
• InChiKey: RSXHRBXUUIJWEO-ATFXWRRLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Rh((S,S)-DIPAMP)((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF4 、 2,5-降冰片二烯 以 氘代甲醇 为溶剂， 生成 {((R,R)-1,2-bis(phenyl-o-anisoylphosphino)ethane)(norbornadiene)}rhodium tetrafluoroborate
  参考文献：
  名称：

  About the Crystal Structure of [Rh((S,S)-DIPAMP)- ((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl Acrylate)]BF₄:  Major or Minor Catalyst−Substrate Complex?

  摘要：

  Asymmetric hydrogenation of (Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate with [Rh((S,S)-DIPAMP)(MeOH)(2)]BF4 was investigated. Low temperature NMR measurements prove the recently published X-ray structure of [Rh((S,S)-DIPAMP)((Z)-2-benzoylamino-3-(3,4-dimethoxyphenyl)-methyl acrylate)]BF4 to be the major substrate complex. The asymmetric hydrogenation of the prochiral DOPA precursor with the cationic Rh-DIPAMP catalyst therefore follows the "anti-lock-and-key" motif analogue to similar substrate complexes already known from literature.

  DOI：

  10.1021/om0490536