PdCl2(2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol)2 | 1313494-85-7

• 英文名称: PdCl2(2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol)2
• CAS: 1313494-85-7
• 化学式: C₃₄H₃₂Cl₂N₄O₂Pd
• 分子量: 705.98
• InChiKey: RFEBDYKCYBQCKF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 2-(3,5-二苯基吡唑-1-基)乙醇 以 二氯甲烷 为溶剂， 以80%的产率得到PdCl2(2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol)2
  参考文献：
  名称：

  Study of the coordination behaviour of (3,5-diphenyl-1H-pyrazol-1-yl)ethanol against Pd(II), Zn(II) and Cu(II)

  摘要：

  A new easily synthetic route with a 96% yield of ligand 2-(3,5-diphenyl-1H-pyrazol-1-yl)ethanol (L) is obtained. The reactivity of L against Pd(II), Zn(II) and Cu(II) leads to [PdCl2(L)(2)] (1), [ZnCl2(L)] (2) and [CuCl(L')](2) (3) (L' is the ligand L without alcoholic proton), respectively. According to the different geometries imposed by the metallic centre and the capability of L to present various coordination links, it has been obtained complexes with square planar (1 and 3) or tetrahedral (2) geometry and different nuclearity: monomeric (1 and 2) or dimeric (3). Complete characterisation by analytical and spectroscopic methods, resolution of L and 1-3 by single-crystal X-ray diffraction and magnetic studies for complex 3 are presented. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.04.027