[(η5-C5H4CH2NHC6H5)Re(CO)3] | 1058160-93-2

• 英文名称: [(η5-C5H4CH2NHC6H5)Re(CO)3]
• CAS: 1058160-93-2
• 化学式: C₁₅H₁₂NO₃Re
• 分子量: 440.472
• InChiKey: ZZQIOBSYJBLCKX-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  sodium tetrahydroborate 、 [(η5-(E)-C5H4CHNC6H5)Re(CO)3] 以 甲醇 为溶剂， 以99%的产率得到[(η5-C5H4CH2NHC6H5)Re(CO)3]
  参考文献：
  名称：

  Cyrhetrenylimines and cyrhetrenylamines: Synthesis, characterization and X-ray crystal structure

  摘要：

  Cyrhetrenyl Schiff base derivatives of the form (eta(5)-C5H4CH=NAr)Re(CO)(3), [Ar=Ph (1a) C6H4OMe-p (l b) and C6H4NO2-p (1c)] have been prepared from cyrhetrenylcarbaldehyde and the corresponding aromatic amines. H-1 and C-13 NMR indicates that these compounds have the anti-(E) conformation in solution and the X-ray crystal structure of 1b confirms that it also adopts the anti-(E) form in the solid state. Further reaction of cyrhetrenylaldimines 1 with sodium borohydride in methanol produces quantitatively, the corresponding amine derivatives (eta(5)-C5H4CH2-NHAr)Re(CO)(3) [Ar=Ph (2a) C6H4OMe-p (2b) and C6H4NO2-p (2c)]. All these cyrhetrenylamines were characterized by IR,H-1 and C-13 NMR, MS. Additionally, 2b has been characterized structurally. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.04.021