trans-[PdCl(1-phenyl-5-tetrazolyl)(PMe2Ph)2] | 1031838-53-5

• 英文名称: trans-[PdCl(1-phenyl-5-tetrazolyl)(PMe2Ph)2]
• CAS: 1031838-53-5
• 化学式: C₂₃H₂₇ClN₄P₂Pd
• 分子量: 563.315
• InChiKey: KUGYXJFKGKMMFV-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  trans-[PdCl(1-phenyl-5-tetrazolyl)(PMe2Ph)2] 以 二氯甲烷 、 水 为溶剂， 生成 Pd(NCNC6H3-2,6-Me2)(1-phenyl-5-tetrazolyl)(PMe2Ph)2
  参考文献：
  名称：

  Bis(phosphine) Pd(II)–azido complexes containing heterocyclic ligands: Reactivity toward organic isocyanides

  摘要：

  Bis(phosphine) Pd-azido complexes containing heterocycles such as tetrazolyl, pyrazinyl, and thienyl groups reacted with aryl isocyanides to give the corresponding Pd-carbodiimido or -imidoyl carbodiimido complexes. These products were formed by the insertion of the isocyanides into the Pd-N (azido) or the Pd-C (heterocycles) bond. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.10.026