| 1192352-54-7

• CAS: 1192352-54-7
• 化学式: C₇₆H₅₂Cl₂O₅P₄Pt₂
• 分子量: 1630.21
• InChiKey: FTPDJKWNQHZRMR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [PtCl(1,8-bis(diphenylphosphino)anthracene(1-))]*CH2Cl2 在 air 作用下， 以 氯仿 为溶剂， 以62%的产率得到
  参考文献：
  名称：

  Photooxidation of a Platinum-Anthracene Pincer Complex: Formation and Structures of Pt^II-Anthrone and -Ketal Complexes

  摘要：

  Irradiating the cyclometalated pincer complex Pt-II(DPA)Cl (1, DPA = 1,8-bis(diphenylphosphino)anthracene) in the presence of O-2 led to three sequential oxidations of the anthracenyl ring. The first photoproduct, a Pt-II-9, 10-endoperoxide complex, was converted photochemically to a Pt-II-9-hydroxyanthrone complex A which was further oxygenated to a Pt-II-hemiketal (B). The oxidation of A, which could be accelerated by light irradiation, Probably involved a Pt-II-anthraquinone intermediate. B underwent acid-catalyzed ketalization to form a binuclear Pt-2(II)-diketal (B1). The photolysis was followed by UV-vis absorption and NMR spectroscopy, and the structures of A and B1 were characterized by single crystal X-ray diffraction.

  DOI：

  10.1021/ic900479w