chloro(triisopropyl phosphorotrithioite)copper | 745792-76-1

• 英文名称: chloro(triisopropyl phosphorotrithioite)copper
• CAS: 745792-76-1
• 化学式: C₃₆H₈₄Cl₄Cu₄P₄S₁₂
• 分子量: 1421.75
• InChiKey: MSBLIEYEJUYRJZ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  triisopropyl trithiophosphite 、 copper(l) chloride 以 苯 为溶剂， 以50%的产率得到chloro(triisopropyl phosphorotrithioite)copper
  参考文献：
  名称：

  Triisopropyl Phosphorotrithioite as a Monodantate and a Tridentate Ligand in Complexes with Copper(I) Halides

  摘要：

  Triisopropyl phosphorotrithioite reacts with copper(I) halides to form complexes (i-PrS)(3)(PCuX)-Cu-. (X = I, Br, Cl) of a cubic structure with monodentate coordination by the (CuP)-P-... bond. The complex [(i-PrS)(3)P(.)4Cul](n) is formed by disproportionation of diisopropyl phosphorochloridodithioite and has an unusual structure comprising a two-dimensional net of (CuCl)(8) clusters bridged by triisopropyl phosphorotrithioite ligands; a tridentate coordination by one P(III) and two S(II) atoms was first observed in the complex.

  DOI：

  10.1023/b:rugc.0000016013.38120.58