oxodysprosium(III) chloride | 14986-29-9

• 英文名称: oxodysprosium(III) chloride
• 英文别名: dysprosium oxychloride
• CAS: 14986-29-9
• 化学式: ClDyO
• 分子量: 213.952
• InChiKey: RKYXCEJIPSPGPP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.11
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

文献信息

• Synthesis, Structures, and Luminescent Properties of Sodium Rare‐Earth Metal(III) Chloride Oxotellurates(IV), Na ₂ <i>Ln</i> ₃ Cl ₃ [TeO ₃ ] ₄ ( <i>Ln</i> = Sm, Eu, Gd, Tb, Dy, and Ho)
  作者：Dmitri O. Charkin、Sabine Zitzer、Stefan Greiner、Sergey G. Dorofeev、Andrei V. Olenev、Peter S. Berdonosov、Thomas Schleid、Valery A. Dolgikh

  DOI：10.1002/zaac.201700227

  日期：2017.11.17

  β = 135.151(6)° for Ln = Eu, a = 23.928(1), b = 5.5928(1), c = 17.1133(8) A, β = 135.366(3)° for Ln = Gd, a = 23.907(1), b = 5.569(3), c = 16.745(1) A, β = 134.205(3)° for Ln = Tb, a = 23.870(1), b = 5.547(3), c = 16.665(1) A, β = 134.102(3)° for Ln = Dy and a = 23.814(1), b = 5.526(3), c = 16.626(1) A, β = 134.016(3)° for Ln = Ho and Z = 4. Their crystal structure can be considered as a framework

  通过助熔剂技术合成了六种新的氯化钠稀土金属 (III) 氧代碲酸盐 (IV) Na2Ln3Cl3[TeO3]4，与 Na2Y3Cl3[TeO3]4 同构，并通过单晶 XRD 进行表征。化合物在单斜空间群 C2/c 中结晶，晶格常数 a = 23.967(1), b = 5.6342(3), c = 16.952(1) A, β = 134.456(5)° Ln = Sm, a = 23.932(2), b = 5.6044(5), c = 17.134(1) A, β = 135.151(6)° Ln = Eu, a = 23.928(1), b = 5.5928(1), c = 17.1133( 8) A, β = 135.366(3)° Ln = Gd, a = 23.907(1), b = 5.569(3), c = 16.745(1) A, β = 134.205(3)° Ln =
• Thermodynamic re-optimization of the DyCl3–KCl system
  作者：Xianran Xing、Shuyu Dai、Zhenqi Zhu、Toshihiro Tanaka

  DOI：10.1016/s0040-6031(01)00675-x

  日期：2002.2

  The intermediate compounds, K3DyCl6, K2DyCl5 and KDy2Cl7, in the DyCl3-KCl system, are confirmed by X-ray powder diffraction method. With CALPHAD technology the phase diagram of the DyCl3-KCl system is re-optimized and calculated using ChemSage software. A set of thermodynamic functions has been optimized based on an interactive computer-assisted analysis. The calculated phase diagram and optimized thermodynamic parameters are thermodynamically self-consistent. (C) 2002 Elsevier Science B.V. All rights reserved.