Mn(pyrrole-2-carboxaldehyde thiosemicarbazone)2Cl2 | 959396-92-0

• 英文名称: Mn(pyrrole-2-carboxaldehyde thiosemicarbazone)2Cl2
• CAS: 959396-92-0
• 化学式: C₁₂H₁₆Cl₂MnN₈S₂
• 分子量: 462.289
• InChiKey: SSSVECMFYCNKMZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(1H-pyrrol-2-ylmethylene)hydrazinecarbothioamide 、 manganese(ll) chloride 以 乙醇 为溶剂， 以60%的产率得到Mn(pyrrole-2-carboxaldehyde thiosemicarbazone)2Cl2
  参考文献：
  名称：

  Spectral, IR and magnetic studies of Mn(II), Co(II), Ni(II) and Cu(II) complexes with pyrrole-2-carboxyaldehyde thiosemicarbazone (L)

  摘要：

  Mn(II), Co(II), Ni(II) and Cu(II) complexes are synthesized with thiosemicarbazone (L) derived from pyrrole-2-carboxyaldehyde. These complexes are characterized by elemental analysis, molar conductance, magnetic susceptibility measurement, mass, IR, electronic and EPR spectral studies. The molar conductance measurement of the complexes in DMSO indicates that the complexes are non-electrolyte except Co(L)(2)(NO3)(2) and Ni(L)(2)(NO3)(2) complexes which are 1:2 electrolyte. All the complexes are of high-spin type. On the basis of spectral studies an octahedral geometry may be assigned for Mn(II), Co(II) and Ni(II) complexes except Co(L)(2)(NO3)(2) and Ni(L)(2)(NO3)(2) which are of tetrahedral geometry. A tetragonal geometry may be suggested for Cu(II) complexes. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2006.11.053