dichloro(1,2-di(imino-4'-antipyrinyl)ethane)cadmium | 891184-32-0

• 英文名称: dichloro(1,2-di(imino-4'-antipyrinyl)ethane)cadmium
• CAS: 891184-32-0
• 化学式: C₂₄H₂₄CdCl₂N₆O₂
• 分子量: 611.81
• InChiKey: XMNCIOXXHBSFTC-OXBZONAHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-(diimino-4'-antipyrinyl)ethane 、 cadmium(II) chloride 以 甲醇 、 乙酸乙酯 为溶剂， 以87%的产率得到dichloro(1,2-di(imino-4'-antipyrinyl)ethane)cadmium
  参考文献：
  名称：

  Cadmium(II) Complexes of 1,2-Di(Imino- 4′-Antipyrinyl)Ethane

  摘要：

  Cadmium(II) complexes of the Schiff base 1,2-di(imino-4'-antipyrinyl)ethane (GA) having general formulae [Cd(GA)]X-2; (X = NO3- , ClO4-) and [Cd(GA)X-2]; (X = Cl- , Br- or I-) have been synthesized and characterized by elemental analysis, electrical conductance in non-aqueous solvents, infrared and electronic spectra as well as thermogravimetric analysis. In all these complexes, GA acts as a neutral tetradentate ligand coordinating through both the carbonyl oxygens and both the azomethine nitrogens. Both the anions are coordinated in the halide complexes while these remain as counter ions in the perchlorate and nitrate complexes. Thermal decomposition behavior of the nitrate complex indicates that it is stable up to 234 degrees C and undergoes a three-stage decomposition pattern yielding the anhydrous Cadmium(II) oxide as the final residue.

  DOI：

  10.1080/15533170500358135