[((tetramethylcyclopentadienyl)2Y(μ-η1:η2-allyl azoxy))2] | 1257082-64-6

• 英文名称: [((tetramethylcyclopentadienyl)2Y(μ-η1:η2-allyl azoxy))2]
• CAS: 1257082-64-6
• 化学式: C₄₂H₆₂N₄O₂Y₂
• 分子量: 832.792
• InChiKey: KODUETAXKMJLBP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [(tetramethylcyclopentadienyl)2Y(η3-allyl)] 、 一氧化二氮 以 甲苯 为溶剂， 以76%的产率得到[((tetramethylcyclopentadienyl)2Y(μ-η1:η2-allyl azoxy))2]
  参考文献：
  名称：

  Facile Insertion of N₂O into Metal−Carbon Bonds of Metallocene Allyl Complexes to Form (RN₂O)⁻ Ligands

  摘要：

  Attempts to generate a scandium metallocene oxide using N2O have revealed that N2O undergoes facile insertion into metal carbon bonds of allyl meiallocene complexes to form (RN2O)(-) ligands where R = C3H5. This has been demonstrated in reactions with the tetramethylcyclopentadienyl allyl complexes (C5Me4H)(2)M(eta(3)-C3H5)(M = Sc, Y) and the pentamethylcyclopentadienyl allyl compounds (C5Me5)(2)M(eta(3)-C3H5) (M = Y, Sm, La), which generate the insertion products [(C5Me4H)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2) (M = Sc, 1; Y, 2) and [(C5Me5)(2)M(mu-eta(1):eta(2)-ON=NC3H5)](2)(M = Y, 3; Sm, 4; La, 5), respectively.

  DOI：

  10.1021/om100917w