bis(7-amino-2-methyl-4H-chromen-4-one)-N5,N'5-dichlorido-zinc(II)*acetonitrile | 1431569-38-8

• 英文名称: bis(7-amino-2-methyl-4H-chromen-4-one)-N5,N'5-dichlorido-zinc(II)*acetonitrile
• CAS: 1431569-38-8
• 化学式: C₂H₃N*C₂₀H₁₈Cl₂N₂O₄Zn
• 分子量: 527.722
• InChiKey: PIDDWHKDIRDGSK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  7-氨基-2-甲基色酮 、 乙腈 、 zinc(II) chloride 以 乙腈 为溶剂， 反应 2.0h， 以90.32%的产率得到bis(7-amino-2-methyl-4H-chromen-4-one)-N5,N'5-dichlorido-zinc(II)*acetonitrile
  参考文献：
  名称：

  Novel bright-blue luminescent complex of Zn(II) with 7-amino-methylchromen-4-one: Synthesis, photophysical properties and DFT calculations

  摘要：

  A new Zn(II) complex with 7-amino-2-methylchromen-4-one as monodentate ligand has been synthesized and characterized by elemental analysis, MS-FAB, (HNMR)-H-1 and FT-IR spectroscopy. The structure and spectroscopic properties of complex were studied using X-ray crystallography, fluorescence spectroscopy and DFT calculations. The relationship between solid-state fluorescence and molecular packing of ligand and complex were examined. Fluorescence properties of the solid-state complex (intensive bright-blue emission) indicate that it can serve as a potential photoactive material. The complex could also act as sensitive fluorescent probe for Zn(II) in acetonitrile. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.03.035