[Ru(III)Cl([o-(N,N-dimethylamino)phenyl]diphenylphosphine)]2(μ-o)(μ-Cl)2 | 365979-95-9

• 英文名称: [Ru(III)Cl([o-(N,N-dimethylamino)phenyl]diphenylphosphine)]2(μ-o)(μ-Cl)2
• 英文别名: μ-dichloro-μ-oxobis(chloro(o-diphenylphosphino-N,N-dimethylaniline)ruthenium(III))；[RuCl(o-diphenylphosphino-N,N-dimethylaniline)]2(μ-O)(μ-Cl)
• CAS: 365979-95-9
• 化学式: C₄₀H₄₀Cl₄N₂OP₂Ru₂
• 分子量: 970.67
• InChiKey: KGUZHVHLOXKCDI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  RuCl2(o-(diphenylphosphino)-N,N-dimethylaniline)(PPh3) 在 air 作用下， 以 not given 为溶剂， 生成 [Ru(III)Cl([o-(N,N-dimethylamino)phenyl]diphenylphosphine)]2(μ-o)(μ-Cl)2
  参考文献：
  名称：

  Ruthenium(II) Thiol and H₂S Complexes: Synthesis, Characterization, and Thermodynamic Properties

  摘要：

  The known, green, five-coordinate species trans-RuCl2(P-N)(PPh3) react with R'SH thiols to give yellow cis-RuCl2(P-N)(PPh3)(R'SH) products (P-N = o-diphenylphosphino-N,N'-dimethylaniline; R' = alkyl). The MeSH and EtSH compounds are structurally characterized, with the former being the first reported for a transition metal MeSH complex, while the thiol complexes with R' = Pr-n, Pr-i, (n)Pn (pentyl), (n)Hx (hexyl), and Bn (benzyl) are synthesized in situ. Other trans-RuX2(P-N) (PR3) complexes (X = Br, I; R = Ph, p-tolyl) are synthesized, and their H2S adducts, of a type reported earlier by our group, are also prepared. Thermodynamic data are presented for the reversible formation of the MeSH and EtSH complexes and the H2S analogues. The (RuCl2)-Cl-II(P-N)(PPh3) complex in solution decomposes under O-2 to form [(RuCl)-Cl-III(P-N)](2)(mu-O)(mu-Cl)(2).

  DOI：

  10.1021/ic3004118

文献信息

• The Nitrous Oxide Complex, RuCl₂(η¹-N₂O)(P−N)(PPh₃) (P−N = [<i>o</i>-(<i>N,N</i>-Dimethylamino)phenyl]diphenylphosphine); Low Temperature Conversion of N₂O to N₂ and O₂
  作者：Craig B. Pamplin、Erin S. F. Ma、Nasser Safari、Steven J. Rettig、Brian R. James

  DOI：10.1021/ja0106319

  日期：2001.9.1