[Ir(5-(2-pyridyl)thiophene-2-carbaldehyde(1-))2(5,5'-dimethyl-2,2'-dipyridyl)]PF6 | 1207611-00-4

• 英文名称: [Ir(5-(2-pyridyl)thiophene-2-carbaldehyde(1-))2(5,5'-dimethyl-2,2'-dipyridyl)]PF6
• CAS: 1207611-00-4
• 化学式: C₃₂H₂₄IrN₄O₂S₂*F₆P
• 分子量: 897.884
• InChiKey: ZHUMHPRNTWUDOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 5 5'-二甲基-2,2'-二吡啶 、 [Ir(5-(2-pyridyl)thiophene-2-carbaldehyde(1-))2Cl]2 以 甲醇 、 二氯甲烷 为溶剂， 以67%的产率得到[Ir(5-(2-pyridyl)thiophene-2-carbaldehyde(1-))2(5,5'-dimethyl-2,2'-dipyridyl)]PF6
  参考文献：
  名称：

  Electrochemiluminescent Functionalizable Cyclometalated Thiophene-Based Iridium(III) Complexes

  摘要：

  A family of new functional bis-cyclometalated thiophene-based cationic iridium complexes have been prepared and fully characterized. The introduction of formyl groups into the thienyl-based cyclometalating ligand (thpy-CHO) allows one to perform further functionalizability and to confer to the whole species potentially interesting perspectives as functional materials. The X-ray crystal structures of three complexes, namely, [Ir(thpy)(2)bpy]PF6, [Ir(thpy-CHO)(2)bpy]PF6, and [Ir(thpy-CHO)(2)phen]PF6, are reported. A rich reduction voltammetric pattern of the complexes is outlined, and the effect of the substituents on the cyclic voltammetric behavior is fully elucidated. Finally, the electrochemiluminescence spectra of all of the species have been obtained in acetonitrile by annihilation of the one-electron-oxidized and -reduced forms, showing very similar features with respect to the luminescence (as both the shape and energy of the emission bands).

  DOI：

  10.1021/ic901660m