2,3-dimethyl-1-[4-(2-vinyl-phenoxy)-butyl]-imidazolium hexafluorophosphate | 1010107-45-5

• 英文名称: 2,3-dimethyl-1-[4-(2-vinyl-phenoxy)-butyl]-imidazolium hexafluorophosphate
• CAS: 1010107-45-5
• 化学式: C₁₇H₂₃N₂O*F₆P
• 分子量: 416.347
• InChiKey: YAJYBYNJIPSFPG-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Grubbs catalyst first generation 、 2,3-dimethyl-1-[4-(2-vinyl-phenoxy)-butyl]-imidazolium hexafluorophosphate 在 copper(l) chloride 作用下， 以 二氯甲烷 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Ionic imidazolium containing ruthenium complexes and olefin metathesis in ionic liquids

  摘要：

  The preparation of two ionic Hoveyda's type catalysts with an ionic chain, containing an imidazolium salt tag link to the ortho oxygen atom (11) and to the meta-position (12) of the styrenylidene ligand is presented. The catalysts are evaluated in ionic liquid medium: the 1-butyl-3-methyl and 1-butyl-2,3-dimethyl imidazolium salts (bmim)X-+(-) (X=PF6-, NTf2- (bistrifluoromethylsulfonimide)) for RCM of N,N-diallyltosylamide and dimethyldiallylmalonate. The catalysts show good activity for the first cycle with moderate recyclability. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2006.12.016