| 1010069-24-5

• CAS: 1010069-24-5
• 化学式: C₂₃H₂₉ClCuN₄O
• 分子量: 476.508
• InChiKey: YGHATLIFLHTQKC-IXADMPAPSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,4-di-tert-butyl-6-((((E)-1-methyl-1,3-dihydro-2H-benzo[d]imidazol-2-ylidene)hydrazineylidene)methyl)phenol 、 copper dichloride 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Novel mono-and binuclear complexes of Cu(II) with hydrazones of salicylaldehyde derivatives

  摘要：

  A series of new mono-and binuclear metal chelates of Cu(II) with ligands, which are the products of condensation of 3,5-di(tert-butyl)salicylaldehyde with hetarylhydrazines or 4-phenylsemi(thiosemi)carbazide, were synthesized. Their compositions and structures were determined by the elemental analysis, IR and H-1 NMR spectroscopies, magnetochemistry, and conductometry measurements. It was shown for the first time that in the case of hetarylhydrazones, only mononuclear complexes were formed due to steric effect of tert-butyl fragments, whereas arylhydrazones gave binuclear complexes with two Cu atoms bonded by the spin-spin interaction. The exchange parameters 2J were calculated for binuclear metal chelates.

  DOI：

  10.1134/s1070328407040112