((tetramethylcyclam)MnCl)BF4 | 375393-71-8

• 英文名称: ((tetramethylcyclam)MnCl)BF4
• 英文别名: ((tmc)MnCl)BF4
• CAS: 375393-71-8
• 化学式: BF₄*C₁₄H₃₂ClMnN₄
• 分子量: 433.63
• InChiKey: BZRXTJOQXBLGRW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4,8,11-四甲基-1,4,8,11-四氮环十四烷 、 tetrabutylammonium tetrafluoroborate 、 manganese(ll) chloride 以 乙腈 为溶剂， 以75%的产率得到((tetramethylcyclam)MnCl)BF4
  参考文献：
  名称：

  Synthesis, X-ray Structure, Electrochemical, and EPR Studies of a Pentacoordinated Mn(II) Tetramethylcyclam Complex

  摘要：

  The synthesis and full characterization of [(tmc)MnCl].X (where tine is 1,4,8,11-tetramethyl-1,4,8,1 1-tetraazacyclotetradecane and X is BPh4- or BF4-) are reported. The complex is of type I geometry. The manganese ion is pentacoordinated by the four tertiary nitrogen atoms of the macrocycle and one axial chloride. Variable-temperature magnetic susceptibility da ta indicate that the oxidation state of the manganese ion is +II with S = 5/2. The EPR spectrum exhibits unusual signals, with the main derivative line at g = 3.7 and transitions at more than 900 mT. The cyclic voltammogram of this derivative consists of two reversible systems at +1.14 and +1.36 V vs SCE related by a chemical equilibrium attributed to an isomerization process.

  DOI：

  10.1021/ic001472h