cis,trans-N(4),N'(4)-adipoyl-bis[PtCl2(OH)2-1,2,4-triaminobutane] | 250125-54-3

• 英文名称: cis,trans-N(4),N'(4)-adipoyl-bis[PtCl2(OH)2-1,2,4-triaminobutane]
• CAS: 250125-54-3；250125-59-8；763908-44-7
• 化学式: C₁₄H₃₆Cl₄N₆O₆Pt₂
• 分子量: 916.448
• InChiKey: YYWUZWBXWYVCOW-HOCWARKJSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 cis,trans-N(4),N'(4)-adipoyl-bis[PtCl2(OH)2-1,2,4-triaminobutane] 以 盐酸 为溶剂， 生成 N(4),N'(4)-adipoyl-bis[PtCl4-1,2,4-triaminobutane]
  参考文献：
  名称：

  Platinum(IV) complexes of vicinal-1,2-diamines and bis(vicinal-1,2-diamines) with an acylamino function. Evidence for a platinum hydroperoxide intermediate upon oxidation

  摘要：

  By oxidation of mononuclear and dinuclear platinum(II) complexes having as ligands N4-acylated 1,2,4-triaminobutane units with H2O2 an intermediate was observed, probably a platinum bound hydroperoxide which is stabilized by hydrogen bonding to the acyl function in the side chain. Such an intermediate could not be isolated in the oxidation of [Cl2PtLLPtCl2] to the platinum(IV) complexes [(Ho)(2)Cl2PtLLPtCl2(OH)(2)] (LL = 1,2,9,10-tetraaminodecane or 1,2,11,12-tetraaminododecane). The synthesis of several mononuclear and dinuclear diamine tetrachloro platinum(IV) complexes is reported. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05594-1
• 作为产物：
  描述：

  N,N'-bis(3,4-diaminobutyl)hexanediamide;dichloroplatinum 、 双氧水 以 水 为溶剂， 生成 cis,trans-N(4),N'(4)-adipoyl-bis[PtCl2(OH)2-1,2,4-triaminobutane]
  参考文献：
  名称：

  Platinum(IV) complexes of vicinal-1,2-diamines and bis(vicinal-1,2-diamines) with an acylamino function. Evidence for a platinum hydroperoxide intermediate upon oxidation

  摘要：

  By oxidation of mononuclear and dinuclear platinum(II) complexes having as ligands N4-acylated 1,2,4-triaminobutane units with H2O2 an intermediate was observed, probably a platinum bound hydroperoxide which is stabilized by hydrogen bonding to the acyl function in the side chain. Such an intermediate could not be isolated in the oxidation of [Cl2PtLLPtCl2] to the platinum(IV) complexes [(Ho)(2)Cl2PtLLPtCl2(OH)(2)] (LL = 1,2,9,10-tetraaminodecane or 1,2,11,12-tetraaminododecane). The synthesis of several mononuclear and dinuclear diamine tetrachloro platinum(IV) complexes is reported. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05594-1