di-μ-chloro-bis[(1,2,3-η)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium | 952034-11-6

• 英文名称: di-μ-chloro-bis[(1,2,3-η)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium
• CAS: 952034-11-6
• 化学式: C₁₂H₁₈Cl₂O₆Pd₂
• 分子量: 542.017
• InChiKey: UYQXQUIFEMXZFG-RPYXYGEHSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 di-μ-chloro-bis[(1,2,3-η)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium 、 sodium chloride 以 水 为溶剂， 生成 山梨酸 、 sodium tetrachloropalladate(II)
  参考文献：
  名称：

  Palladium η3-allyl complex with sorbic acid: Kinetics and mechanism of protodemetalation in aqueous solutions

  摘要：

  The allyl complex di-mu-chloro-bis[(1,2,3-eta)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium (which is a hydroxyl-containing palladium 11 Sally] complex based on sorbic acid) has been synthesized from trans,trans-2,4-hexadienic (sorbic) acid and Na2PdCl4 in an aqueous solution. The complex has been isolated from the reaction solution and has been characterized by IR, H-1 NMR, and C-13 NMR spectroscopy. Its composition has been determined by elemental analysis. The protodemetalation kinetics of the complex in aqueous solutions has been studied. The rate of this reaction obeys a second-order equation, first-order with respect to each reactant. A reaction mechanism has been derived from protodemetalation kinetics and data characterizing the state of the reactants.

  DOI：

  10.1134/s0023158406060073
• 作为产物：
  描述：

  山梨酸 、 sodium tetrachloropalladate(II) 、 水 在 sodium chloride 作用下， 以 水 为溶剂， 生成 di-μ-chloro-bis[(1,2,3-η)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium
  参考文献：
  名称：

  Palladium η3-allyl complex with sorbic acid: Kinetics and mechanism of protodemetalation in aqueous solutions

  摘要：

  The allyl complex di-mu-chloro-bis[(1,2,3-eta)-1-carboxy-3-(1-hydroxyethyl)allyl]dipalladium (which is a hydroxyl-containing palladium 11 Sally] complex based on sorbic acid) has been synthesized from trans,trans-2,4-hexadienic (sorbic) acid and Na2PdCl4 in an aqueous solution. The complex has been isolated from the reaction solution and has been characterized by IR, H-1 NMR, and C-13 NMR spectroscopy. Its composition has been determined by elemental analysis. The protodemetalation kinetics of the complex in aqueous solutions has been studied. The rate of this reaction obeys a second-order equation, first-order with respect to each reactant. A reaction mechanism has been derived from protodemetalation kinetics and data characterizing the state of the reactants.

  DOI：

  10.1134/s0023158406060073