[Sb( 1,10-phenanthroline)Cl₃] | 1567839-01-3

• 英文名称: [Sb( 1,10-phenanthroline)Cl₃]
• 英文别名: [Sb(phen)Cl₃]；[Sb(1,10-phenanthroline)Cl3]
• CAS: 1567839-01-3；26202-49-3；28425-50-5
• 化学式: C₁₂H₈Cl₃N₂Sb
• 分子量: 408.318
• InChiKey: KIGXYYQSQZLRRB-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 三氯化锑 反应 3.0h， 生成 [Sb( 1,10-phenanthroline)Cl₃]
  参考文献：
  名称：

  锑 (III) 和铋 (III) 与 2,2'-联吡啶和 1,10-菲咯啉配合物的合成、热化学和量子化学研究

  摘要：

  摘要 [SbCl3(L)] 和 [BiBr3(L)] 配合物的热化学研究，其中 L 是 2,2'-联吡啶 (bpy) 或 1,10-菲咯啉 (phen)，通过溶液中的量热测量进行。通过元素分析、FTIR光谱和热分析合成并表征了配合物。从配合物、盐和配体的溶解焓结合辅助热力学数据，利用热化学循环确定了配合物的一些热化学参数。使用M06-2X/def2-TZVPP方法对配合物进行理论研究。考虑到碎片的重组能量，获得了供体-受体键能。我们的研究结果表明，受体金属三卤化物 MX3 (113-136 kJ·mol-1) 的重组能和苯酚的刚性控制着配合物的解离能。理论结果表明，配合物的化学稳定性依次为[BiBr3(phen)] > [SbCl3(phen)] > [BiBr3(bpy)] > [SbCl3(bpy)]，与实验配位焓一致固体状态。

  DOI：

  10.1016/j.tca.2019.05.005

文献信息

• Antimony-121 Mössbauer and infrared spectral studies on 1,10-phenanthroline adducts of antimony(III) halides
  作者：N. Bertazzi、G. Alonzo、T.C. Gibb

  DOI：10.1016/s0020-1693(00)90835-1

  日期：1983.1

  solid state by infrared and Mossbauer spectroscopic techniques. The structures of the antimony trihalide complexes appear to be based on halogen bridged polymers in which the stereochemical activity of the lone pair of electrons varies with the halogen, the highest p-character of the lone pair being observed with the trifluoride adduct. Mossbauer results for the PhSbI 2 complexes suggest a ψ-octahedral

  摘要描述了1,10-菲咯啉与SbX 3（X = F，Cl，Br）和PhSbI 2的单加合物的合成。这些化合物和2,2'-联吡啶与PhSbI 2之间的1：1加合物已主要通过红外和莫斯鲍尔光谱技术表征为固态。三卤化锑复合物的结构似乎是基于卤素桥联的聚合物，其中孤电子对的立体化学活性随卤素而变化，孤对电子的最高p-特征是通过三氟化物加合物观察到的。MoSsbauer的PhSbI 2配合物结果表明ψ-八面体立体化学，其中孤对和Ph基处于反式位置。
• Complexes of different nitrogen donor heterocyclic ligands with SbCl3 and PhSbCl2 as potential antileishmanial agents against SbIII-sensitive and -resistant parasites
  作者：Edgar H. Lizarazo-Jaimes、Priscila G. Reis、Filipe M. Bezerra、Bernardo L. Rodrigues、Rubens L. Monte-Neto、Maria N. Melo、Frédéric Frézard、Cynthia Demicheli

  DOI：10.1016/j.jinorgbio.2013.12.001

  日期：2014.3

  from those responsible for the resistance of Leishmania to Sb(OH)3. In the case of the complexes with PhSbCl2, our data supports the model that both ligand and metal contributed to the overall activity of the complex. Furthermore, among the complexes with SbCl3, only bipy showed an improved activity upon complexation. Cytotoxicity evaluations of these compounds against murine peritoneal macrophages showed

  具有氮供体杂环配体2,2'-联吡啶（bipy），1,10-菲咯啉（phen）或二吡啶[3,2-d：2'，3'-f]喹喔啉（dpq）的新型三价锑配合物具有通过与SbCl 3或PhSbCl 2反应而合成。确定了[Sb（phen）Cl 3 ]和[PhSb（phen）Cl 2 ] CH 3 COOH的晶体结构，并证明它们采用了具有五坐标Sb中心的扭曲方锥几何形状。出人意料的是，所有配合物，配体和PhSbCl 2都显示出很高的抗菌活性，IC 50在纳摩尔浓度范围内对Sb III敏感和耐药的婴儿利什曼原虫（同种。利什曼原虫（Leishmania chagasi）和亚马逊利什曼原虫（Leishmania amazonensis）菌株。与旧的三价药物酒石酸锑基钾盐相比，这些化合物对这些利什曼原虫菌株具有更高的活性。发现[PhSb（phen）Cl 2 ] CH 3 COOH络合物是最活泼的化合物，而PhSbCl
• Synthesis, characterizations and crystal structures of antimony(III) complexes with nitrogen-containing ligands
  作者：Han Dong Yin、Jun Zhai

  DOI：10.1016/j.ica.2008.04.012

  日期：2009.1

  Six antimony adducts with N-donor neutral ligands (1,10-phenanthroline, 4,4'-bipyridine) have been obtained following the reaction of antimony halides with phenanthroline and 4,4'-bipyridine. By changing the solvent and stoichiometry, we obtained six different complexes, Sb(phen)Cl(3) (1), Sb(phen)Br(3) (2), Sb(2)(phen)(4)Br(8)(3) and Sb(bpy)Cl(3)(4), Sb(bpy)(2)Cl(3) (5), Sb(bpyH center dot bpyH(2))Br(6) (6) (where phen = 1,10-phenanthroline, bpy = 4,4'-bipyridine). All the complexes have been characterized via elemental analysis, FT-IR and NMR ((1)H, (13)C) spectroscopy. The crystal structures of complexes 2, 3 and 6 have been determined by X-ray single crystal diffraction.The structural analysis show that the coordination sphere around antimony atom in complex 2 is a distorted square pyramid, coordinated by three bromine atoms and two nitrogen atoms from phen. In complex 3, the central antimony atom is six-coordinated through four bromine atoms and two nitrogen atoms forming a distorted octahedral geometry. Besides that, there are also uncoordinated 1,10-phenanthroline bonded by hydrogen bonds and pi-pi stacking interactions, which is rarely observed in previous reports. The crystal structure of complex 6 consists of bpyH center dot bpyH(2) trications and hexabromoantimonate trianions. The antimony atom in the anion has a distorted octahedral environment. Additionally, all complexes present a 3D framework built up by N-H center dot center dot center dot Br, C-H center dot center dot center dot Br and C-H center dot center dot center dot Cl weak hydrogen bonds interactions. (C) 2008 Elsevier B.V. All rights reserved.