cis-PtCl(1,3-dimethylcyanurate)(P(C6H5)3)2*CH2Cl2 | 1354688-12-2

• 英文名称: cis-PtCl(1,3-dimethylcyanurate)(P(C6H5)3)2*CH2Cl2
• CAS: 1354688-12-2
• 化学式: CH₂Cl₂*C₄₁H₃₆ClN₃O₃P₂Pt
• 分子量: 996.169
• InChiKey: FRFGZPQSKLZJQZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis-dichlorobis(triphenylphosphine)platinum(II) 、 二氯甲烷 、 1,3-dimethylcyanurate lithium 以 甲醇 为溶剂， 以69%的产率得到cis-PtCl(1,3-dimethylcyanurate)(P(C6H5)3)2*CH2Cl2
  参考文献：
  名称：

  Platinum(II) and palladium(II) complexes containing 1,3-dimethylcyanurate ligand

  摘要：

  New platinum(II) and palladium(II) complexes, cis-[PtCl(DMC)(PPh3)(2)] (1 center dot CH2Cl2) and trans-[PdCl(DMC)(PPh3)(2)] (2 center dot 2CHCl(3)), where DMC = 1,3-dimethylcyanurate, were synthesized and characterized by elemental analysis. IR, H-1 NMR, C-13 NMR, P-31 NMR and FAB mass spectroscopy. The structures of complexes are determined by X-ray diffraction and proved to have a distorted square-planar geometry around the metal ions. Both complexes exhibit a high stability in the solid state. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.11.045