[Ru(CO)2Cl2(4,6-dichloroquinoline-5,8-dione)] | 960587-93-3

• 英文名称: [Ru(CO)2Cl2(4,6-dichloroquinoline-5,8-dione)]
• CAS: 960587-93-3
• 化学式: C₁₁H₃Cl₄NO₄Ru
• 分子量: 456.031
• InChiKey: VMMPMACYEUBGJA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichlorotricarbonylruthenium(II) dimer 、 4,6-dichloroquinoline-5,8-dione 以 乙醇 为溶剂， 以18%的产率得到[Ru(CO)2Cl2(4,6-dichloroquinoline-5,8-dione)]
  参考文献：
  名称：

  Synthesis, structure and properties of ruthenium(II) complexes with quinolinedione derivatives as chelate ligands: Crystal structure of [Ru(CO)2Cl2(6-methoxybenzo[g]quinoline-5,10-dione)]

  摘要：

  The reaction of the dimer complex [{Ru(CO)(3)Cl-2}(2)] with the ligands 4,6-dichloroquinoline-5,8-dione and 6-methoxybenzo[g]quinoline-5, 10-dione in ethanol solution led to the neutral mononuclear complexes of general formula [Ru(CO)(2)Cl-2(kappa(2)-quinolinedione-N,O)]. The complexes were characterized by elemental analysis, IR and RMN spectroscopy, and the molecular structure of [Ru(CO)(2)Cl-2(6-methoxybenzo[g]quinoline-5,10-dione)] was determined by single-crystal X-ray diffraction. The redox chemistry of ligands and complexes was investigated by cyclic voltammetry, and their potential antitumor activity was also evaluated. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.08.014