Reactions between BiCl3 and the anion [Co(CO)4]â under various conditions afford some new products: the anion [BiCo(CO)4}4]â, the neutral tetrahedral cluster [BiCo3(CO)9], and the paramagnetic cluster [Bi2Co4(CO)11]â containing a Bi2Co4 array formed by three face-to-face condensed tetrahedral units.
BiCl3与阴离子[Co(CO)4]在各种条件下的反应会产生一些新的产物:阴离子[BiCo(CO)4}4]、中性四面体簇[BiCo3(CO)9]和顺磁性簇[Bi2Co4(CO)11],其中Bi2Co4阵列由三个面对面缩合的四面体单元组成。