摘要:
The heterometallic cluster [Os6Pd(CO)18(bipy)] (bipy = 2,2'-bipyridine) has been isolated in moderate yield from the reaction of [Os3(CO)10(MeCN)2] and [Pd(bipy) (CO2Me)2], and shown by a single-crystal X-ray structure analysis to contain a monocapped octahedral metal core with the palladium occupying one vertex of the octahedron.