[Ir(2-phenylpyridinato)2(CO)(NCMe)][OTf] | 1003273-84-4

• 英文名称: [Ir(2-phenylpyridinato)2(CO)(NCMe)][OTf]
• CAS: 1003273-84-4
• 化学式: CF₃O₃S*C₂₅H₁₉IrN₃O
• 分子量: 718.736
• InChiKey: WHBCSNIWRDVQTD-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Ir(2-phenylpyridinato)2Cl(CO)] 、 propargylamine 、 silver trifluoromethanesulfonate 以 not given 为溶剂， 生成 [Ir(2-phenylpyridinato)2(CO)(NCMe)][OTf]
  参考文献：
  名称：

  Blue‐Light‐Emitting Complexes: Cationic (2‐Phenylpyridinato)iridium(III) Complexes with Strong‐Field Ancillary Ligands

  摘要：

  AbstractThe emission λmax are strikingly shorter (451, 482 nm) for the cationic dicarbonyl complex [Ir(ppy)2(CO)2]+ (2a) than those (473, 495 nm) of the anionic dicyano complex [Ir(ppy)2(CN)2]–, where CO and CN– are both sp carbon coordinating ligands and known to be strong‐field ligands showing a high trans effect. Sky‐blue‐light emission (λmax = 441–443 and 470–471 nm) could be obtained by modifying the ppy ligand to F2Meppy (2,4‐difluoro‐2‐phenyl‐m‐methylpyridinato anion) to prepare [Ir(F2Meppy)2LL′]+ [LL′ = (CO)2 (2aF2Me), (PPh2Me)2 (2bF2Me)]. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

  DOI：

  10.1002/ejic.200600920