2-benzylpyridinium tetrachloraurate(III) | 1416014-91-9

• 英文名称: 2-benzylpyridinium tetrachloraurate(III)
• CAS: 1416014-91-9
• 化学式: AuCl₄*C₁₂H₁₂N
• 分子量: 509.012
• InChiKey: KQHHGVIQTFOVGL-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-苄基吡啶 、 chloroauric acid 以 乙醇 为溶剂， 反应 5.0h， 生成 2-benzylpyridinium tetrachloraurate(III)
  参考文献：
  名称：

  Structural and spectroscopic studies of Au(III) and Pd(II) chloride complexes and organometallics with 2-benzylpyridine

  摘要：

  Au(III) and Pd(II) chloride complexes with 2-benzylpyridine (2bzpy) - [Au(2bzpy)Cl-3] and trans-[Pd(2bzpy)(2)Cl-2], as well as Au(III) chloride organometallics with monoanionic form of 2bzpy, deprotonated in the benzyl side group at the ortho-carbon C(2') (2bzpy*) - [Au(2bzpy*)Cl-2], were studied by H-1, C-13 and N-15 NMR. H-1, C-13 and N-15 coordination shifts (i.e. differences of chemical shifts for the same atom in the complex and ligand molecules) were discussed in relation to the molecular structures and the coordination modes, as well as to the factors influencing nuclear shielding. Analogous NMR measurements were performed for the new (2bzpyH)[AuCl4] salt, studied also by single crystal X-ray diffraction. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.08.005