{Re(CO)₃}₃(μ₂-Im)₃(μ₃-1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene) | 1507340-00-2

• 英文名称: {Re(CO)₃}₃(μ₂-Im)₃(μ₃-1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene)
• CAS: 1507340-00-2
• 化学式: C₅₁H₃₉N₁₂O₉Re₃
• 分子量: 1522.57
• InChiKey: HLZUINZUIVIQFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十羰基二铼 、 N,N'-羰基二咪唑 、 1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene 以 甲苯 为溶剂， 反应 72.0h， 以68%的产率得到{Re(CO)₃}₃(μ₂-Im)₃(μ₃-1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene)
  参考文献：
  名称：

  A Molecular Triangle as a Precursor Toward the Assembly of a Jar-Shaped Metallasupramolecule

  摘要：

  The reaction of Re-2(CO)(10) and 1,1'-carbonyldiimidazole in toluene afforded the molecular triangle [Re-3(mu(2)-Im)(3)(CO)(12)] (1; Im = imidazolate). This air-stable complex 1 acted as a precursor, which could then be further transformed into the complex [{Re(CO)(3)}(3)(mu(2)-Im)(3)(mu(3)-L)] (2.; L = 1,3,5-tris(benzimidazol-1-ylmethyl)-2,4,6-trimethylbenzene) upon reaction with the flexible ligand L under solvothermal conditions. Complex 2 can also be produced directly in a one-pot reaction from Re-2(CO)(10), 1,1'-carbonyldiimidazole, and the flexible ligand L. A single-crystal X-ray diffraction analysis showed that compound 1 has a triangular-shaped structure, which is the smallest rhenium triangle known, as of this writing. Complex 2 adopted a jar-shaped structure. The photophysical properties of complexes 1 and 2 were studied.

  DOI：

  10.1021/om4005065