| 51377-79-8

• CAS: 51377-79-8
• 化学式: H₃S
• 分子量: 37.0238
• InChiKey: RWSOTUBLDIXVET-NJFSPNSNSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  -0.81
• 重原子数：
  1.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  sulphonium 、 硫化氢 以 gaseous matrix 为溶剂， 生成
  参考文献：
  名称：

  Reactions of the H_nS⁺ ions (n = 0 to 3) with several molecular gases at thermal energies

  摘要：

  The rate coefficients and product ion distributions have been determined at room temperature for the reactions of the ions HnS+ (n = 0 to 3) with several diatomic and polyatomic gases. The reactions generally proceed at or near the collisional limit, often generating multiple products. Charge transfer, proton transfer, and atom abstraction, in some cases occurring in parallel, are evident within the data array, emphasizing the complexity of these reactions. The results obtained for the near-thermoneutral reactions of S+ and HS+ with H2S have provided values for the recombination energies of HS+ and H2S+ ions which, within the limitations of the assumptions made, are more closely defined than the previous values.

  DOI：

  10.1063/1.442498

文献信息

• Huntress, W. T.; Pinizzotto, R. F., Journal of Chemical Physics, 1973, vol. 59, p. 4742 - 4756
  作者：Huntress, W. T.、Pinizzotto, R. F.

  DOI：——

  日期：——
• Ruska, W. E. W.; Franklin, J. L., International Journal of Mass Spectrometry and Ion Physics, 1969, vol. 3, p. 221 - 238
  作者：Ruska, W. E. W.、Franklin, J. L.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: S: SVol.4a/b, 1.3.8.7, page 206 - 211
  作者：

  DOI：——

  日期：——
• Franklin, J. L.; Ruska, W. E. W., Chemical Abstracts, AD-689518 (1969) 1/14, 1969, vol. 71, p. 105329
  作者：Franklin, J. L.、Ruska, W. E. W.

  DOI：——

  日期：——
• Reactions of thermal energy ions. Part 5.—Ion-molecule reactions in hydrogen sulphide
  作者：A. G. Harrison、J. C. Thynne

  DOI：10.1039/tf9666203345

  日期：——