chloro(N,N-dimethyl-glycinato)(η⁵-pentamethylcyclopentadienyl)iridium(III) | 1417560-47-4

• 英文名称: chloro(N,N-dimethyl-glycinato)(η⁵-pentamethylcyclopentadienyl)iridium(III)
• CAS: 1417560-47-4
• 化学式: C₁₄H₂₃ClIrNO₂
• 分子量: 465.015
• InChiKey: SUOYOJXAHSPFKS-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis[dichloro(pentamethylcyclopentadienyl)iridium(III)] 、 N,N-二甲基甘氨酸 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以73%的产率得到chloro(N,N-dimethyl-glycinato)(η⁵-pentamethylcyclopentadienyl)iridium(III)
  参考文献：
  名称：

  Selective Alkylation of Amines with Alcohols by Cp*–Iridium(III) Half-Sandwich Complexes

  摘要：

  [(CpIr)-Ir-star(Pro)Cl] (Pro = prolinato) was identified among a series of Cp-star-iridium half-sandwich complexes as a highly reactive and selective catalyst for the alkylation of amines with alcohols. It is active under mild conditions in either toluene or water without the need for base or other additives, tolerates a wide range of alcohols and amines, and gives secondary amines in good to excellent isolated yields.

  DOI：

  10.1021/ol303075h