1,1'-bis(di-tert-butylthiophosphinoyl)ferrocene | 910482-94-9

• 英文名称: 1,1'-bis(di-tert-butylthiophosphinoyl)ferrocene
• CAS: 910482-94-9
• 化学式: C₂₆H₄₄FeP₂S₂
• 分子量: 538.562
• InChiKey: UAGLOCJBOGDYAE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-bis(di-tertbutylphosphino)ferrocene 、 sulfur 以 氯仿 为溶剂， 反应 24.0h， 以70%的产率得到1,1'-bis(di-tert-butylthiophosphinoyl)ferrocene
  参考文献：
  名称：

  第12组具有1,1'-双（膦酰基）二茂铁配体的过渡金属配合物

  摘要：

  报道了四种具有1,1'-双（膦酰基）二茂铁配体的新型镉和锌配合物及其膦硫族化物衍生物的合成。通过元素分析和IR，1 H NMR，31 P NMR和电子吸收光谱对络合物进行表征。dichlorido的晶体结构[1-diphenylphosphinoyl -1' - （二-叔-butylphosphanyl）二茂铁- κ 2 ö，P ]镉（II），[氯化镉2 {（C 17 ħ 14 OP）（C 13 H ^ 22 P ）的Fe}]或氯化镉2（κ 2 P，ø -dppOdtbpf）（1），双[μ-（叔丁基）（1'- diphenylphosphinoylferrocen -1-基）次膦酸根-κ 3 ö，Ö '：ø '']双[chloridozinc（II）]，[锌2 {（C 9 ħ 13 Ò 2 P）（C 17 H ^ 14 OP）的Fe} 2氯2 ]或[ZnOCl {κ 2 ö，ø '-Ph 2

  DOI：

  10.1107/s2053229621004162

文献信息

• Anodic Electrochemistry of Free and Coordinated 1,1‘-Bis(di-<i>tert</i>-butylphosphino)ferrocene
  作者：Fawn N. Blanco、Laura E. Hagopian、William R. McNamara、James A. Golen、Arnold L. Rheingold、Chip Nataro

  DOI：10.1021/om051011+

  日期：2006.8.1

  The electrochemistry of 1,1'-bis(di-tert-butylphosphino) ferrocene (dtbpf) was examined in methylene chloride with tetrabutylammonium hexafluorophosphate as the supporting electrolyte. Two new complexes in which dtbpf was bound to a transition metal were prepared and characterized. The two new complexes as well as two previously reported complexes were analyzed by cyclic voltammetry. In addition, the chalcogenids, dtbpfS(2) and dtbpfSe(2), were prepared and characterized by NMR and the structure of dtbpfSe(2) was determined. The oxidation of dtbpfS(2) is a simple one-electron process due to the presence of the iron center. In contrast, the oxidation of dtbpfSe(2) is electrochemically irreversible and appears to proceed by an EE mechanism. Chemical oxidation of dtbpfSe(2) resulted in the formation of [dtbpfSe(2)][BF4](2), in which a Se-Se bond formed. This compound was characterized by P-31 NMR and X-ray crystallography. A detailed analysis of the electrochemistry suggests that the oxidation of dtbpfSe(2) occurs by two separate one-electron processes. In addition, formation of the Se-Se bond was reversible.