| 1161437-88-2

• CAS: 1161437-88-2
• 化学式: C₁₉H₁₈Cl₂N₂Pd
• 分子量: 451.691
• InChiKey: HWYAXIZJGKFBMQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 N-(phenylmethyl)-1-phenyl-2-pyridine methanamine 以 甲醇 为溶剂， 以92%的产率得到
  参考文献：
  名称：

  N‐Heterocyclic Benzhydrylamines as New N , N ‐Bidentate Ligands in Palladium Complexes: Synthesis, Characterization and Catalytic Activity

  摘要：

  AbstractThe synthesis of new N,N‐bidentate ligands based on a π‐deficient N‐heterocyclic benzhydrylamine core is described. The corresponding air‐stable palladium complexes are obtained in high yields and fully characterized by NMR spectroscopy and X‐ray structure determination. These new phosphane‐free catalytic systems proved efficient in the Suzuki–Miyaura reaction, enabling us to obtain biaryl products in good yields, also for reactions with o‐substituted phenyl chlorides as starting materials. The effects of both electronic and steric modulations at the benzhydrylamine core on the catalytic activity are also described.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

  DOI：

  10.1002/ejic.200800154