[Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] | 155111-16-3

• 英文名称: [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]
• 英文别名: [Ir2(μ-SC6F5)2(cod)2]
• CAS: 155111-16-3
• 化学式: C₂₈H₂₄F₁₀Ir₂S₂
• 分子量: 999.055
• InChiKey: YZJKKPIBVAAPHX-MIXQCLKLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  正己烷 、 [Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2] 、 2,6-二甲基苯基异腈 以 二氯甲烷 为溶剂， 以4%的产率得到[Ir3(μ-SC6F5)2(SC6F5)(μ,μ'-xylyl isocyanide)(xylyl isocyanide)4(cod)](n-hexane)
  参考文献：
  名称：

  Thiolate complexes of iridium. Structures of [Ir2(μ-SC6F5)2(cod)2], [Ir(SC6F5)(H)(SiPh3)(XNC)3] and [Ir3(μ-SC6F5)2(SC6F5)(μ,μ′-XNC)(XNC)4(cod)] (XNC=xylyl isocyanide)

  摘要：

  The complex [Ir(2)(mu-SC(6)F(5))(2)(cod)(2)] (1) (cod = 1,5-cyclooctadiene), readily prepared in good yield from [Ir(2)(mu-OMe)(2)(cod)(2)], combines with Ph(3)SiH and XNC (XNC = 2,6-dimethylphenylisocyanide, xylyl isocyanide) in benzene to give [Ir(SC(6)F(5))(H)(SiPh(3))-(XNC)(3)] (2). With XNC alone, in CH(2)Cl(2), 1 reacts to give, among other, unidentified products, [Ir(3)(mu-SC(6)F(5))(2)(SC(6)F(5))(mu,mu'-XNC)(XNC)(4)(cod)] (3). The X-ray crystal structures of 1, 2 and 3 are reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.001
• 作为产物：
  描述：

  (1,5-cyclooctadiene)(methoxy)iridium(I) dimer 、 五氟苯硫酚 以 二氯甲烷 为溶剂， 以75%的产率得到[Ir2(μ-SC6F5)2(1,5-cyclooctadiene)2]
  参考文献：
  名称：

  Thiolate complexes of iridium. Structures of [Ir2(μ-SC6F5)2(cod)2], [Ir(SC6F5)(H)(SiPh3)(XNC)3] and [Ir3(μ-SC6F5)2(SC6F5)(μ,μ′-XNC)(XNC)4(cod)] (XNC=xylyl isocyanide)

  摘要：

  The complex [Ir(2)(mu-SC(6)F(5))(2)(cod)(2)] (1) (cod = 1,5-cyclooctadiene), readily prepared in good yield from [Ir(2)(mu-OMe)(2)(cod)(2)], combines with Ph(3)SiH and XNC (XNC = 2,6-dimethylphenylisocyanide, xylyl isocyanide) in benzene to give [Ir(SC(6)F(5))(H)(SiPh(3))-(XNC)(3)] (2). With XNC alone, in CH(2)Cl(2), 1 reacts to give, among other, unidentified products, [Ir(3)(mu-SC(6)F(5))(2)(SC(6)F(5))(mu,mu'-XNC)(XNC)(4)(cod)] (3). The X-ray crystal structures of 1, 2 and 3 are reported. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.03.001