| 934990-32-6

• CAS: 934990-32-6
• 化学式: C₇₈H₆₀N₈P₂Ru₃
• 分子量: 1474.55
• InChiKey: NNRJRJIBYMNOLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-((C5H5)(P(m-Tol)3)2RuCCC5H4)2Ru 、 四氰基乙烯 以 二氯甲烷 为溶剂， 以44%的产率得到
  参考文献：
  名称：

  Trimetallic complexes containing 1,1′-Rc′(CC)2 units [Rc′=ruthenocene-1,1′-diyl, Ru(η-C5H4–)2]

  摘要：

  Reactions between 1,1'-(Me3SiC equivalent to C)(2)Rc' [Rc' = ruthenocen-1, 1'-diyl, Ru(eta-C5H4-)(2)] and RuCl(PP)Cp' in the presence of KF gave 1,1'-{Cp(PP)RuC equivalent to C}(2)Rc' [Cp' = CP, PP = PPh3 1, P(m-tol)(3) 2, dppe 3, dppf 4; Cp' = Cp*, PP = dppe 5]. Compounds 1 and 2 react with tcne to give two diastereomers a/b of the allylic (vinylcarbene) complexes 6 and 7, while methylation of 5 gave the bis-vinylidene [1,1'-{Cp*(dppe)Ru=C=CMe}2Rc'](BPh4)(2) (8). The X-ray structures of 4, 6b and 8 have been determined. Cyclic voltammograms indicate that there is some electronic communication between the ruthenium end-groups through the Rc' centre. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.11.037